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Details of Award

NERC Reference : NER/B/S/2002/00513

Fe(III) in freshwaters: organic complexation and solubility control.

Grant Award

Principal Investigator:
Professor E Tipping, NERC CEH (Up to 30.11.2019), NERC CEH - Windermere
Co-Investigator:
Dr J Hamilton-Taylor, Lancaster University, Lancaster Environment Centre
Science Area:
Freshwater
Overall Classification:
Freshwater
ENRIs:
Pollution and Waste
Natural Resource Management
Science Topics:
Water Quality
Pollution
Biogeochemical Cycles
Land - Ocean Interactions
Abstract:
Prediction of the solubility of ferric iron in freshwaters is a long-standing challenge in aquatic chemistry. Recent progress in the modelling of cation binding by natural organic matter has led to a theoretical basis for calculating concentrations of truly-dissolved Fe(III), i.e. the sum of inorganic solution species plus dissolved organic complexes. We are now able to test the hypothesis that the activity of Fe3+ is governed by the dissolution-precipitation reactions of (colloidal) iron oxides, ubiquitous components of freshwaters. This will be done by using ultrafiltration to estimate concentrations of truly-soluble Fe(III) in a range of freshwaters, and by performing speciation calculations with WHAM6, a speciation code incorporating a comprehensive model of metal-organic interactions.
Period of Award:
6 Jun 2003 - 5 Sep 2004
Value:
£27,907
Authorised funds only
NERC Reference:
NER/B/S/2002/00513
Grant Stage:
Completed
Scheme:
Small Grants Pre FEC
Grant Status:
Closed
Programme:
Small Grants

This grant award has a total value of £27,907  

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FDAB - Financial Details (Award breakdown by headings)

Total - StaffTotal - T&STotal - Other CostsTotal - Indirect Costs
£15,437£777£4,592£7,102

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