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Details of Award

NERC Reference : NER/B/S/2002/00319

Development of a field instrument to measure the chemical lifetime of OH.

Grant Award

Principal Investigator:
Professor DE Heard, University of Leeds, Sch of Chemistry
Co-Investigator:
Professor M Pilling, University of Leeds, Sch of Chemistry
Science Area:
Atmospheric
Overall Classification:
Atmospheric
ENRIs:
Pollution and Waste
Global Change
Science Topics:
Pollution
Tropospheric Processes
Atmospheric Kinetics
Climate & Climate Change
Abstract:
The comparison of OH measurements with the calculations of constrained models is used to probe our understanding of chemical mechanisms in the troposphere. The modelled OH is often higher than measured, and missing sinks in the model have been postulated to explain the discrepancy. We propose to build an instrument to measure the chemical lifetime of OH, tau OH, that is given by the reciprocal of the sum of pseudo-first-order rate coefficients for reaction of OH, and compare it with the calculated tau OH using measured VOCs, NO2 and other sinks. The instrument will use an atmospheric pressure flow tube, with a sliding OH injector, that is sampled by a FAGE fluorescence cell, in which OH will be detected with excellent sensitivity. The new instrument will use some of the 308 nm radiation from the FAGE laser system, and will measure tau OH simultaneously with [OH] and [HO2].
Period of Award:
3 Feb 2003 - 2 Feb 2004
Value:
£30,301
Authorised funds only
NERC Reference:
NER/B/S/2002/00319
Grant Stage:
Completed
Scheme:
Small Grants Pre FEC
Grant Status:
Closed
Programme:
Small Grants

This grant award has a total value of £30,301  

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FDAB - Financial Details (Award breakdown by headings)

Total - StaffTotal - T&STotal - Other CostsTotal - Indirect CostsTotal - Equipment
£975£567£19,841£449£8,469

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