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Details of Award

NERC Reference : NER/A/S/2003/00489

Redox and colloidal iron biogeochemistry in surface Atlantic waters and its role in ocean productivity.

Grant Award

Principal Investigator:
Professor PJ Worsfold, University of Plymouth, Sch of Earth Ocean and Environment
Co-Investigator:
Professor EP Achterberg, University of Southampton, Sch of Ocean and Earth Science
Co-Investigator:
Dr M Gledhill, University of Southampton, Sch of Ocean and Earth Science
Science Area:
Marine
Overall Classification:
Marine
ENRIs:
Natural Resource Management
Global Change
Biodiversity
Science Topics:
Biogeochemical Cycles
Ocean - Atmosphere Interact.
Survey & Monitoring
Climate & Climate Change
Abstract:
Iron is an essential nutrient for marine organisms and plays an important role in primary productivity in the ocean and hence the uptake and production of gases associated with climate change such as carbon dioxide. There are currently, however, large gaps in our knowledge of iron chemistry, its distribution in the oceans and its relationship with biota. The extreme insolubility and biogeochemical reactivity of iron in seawater results in very low dissolved iron concentrations (<1.0 nanomolar) in the open ocean. It is particularly important to determine the lower redox state, Fe(II), because of its greater solubility, potential bioavailability to organisms and its role in photochemically and microbially driven redox processes. However, Fe(II) is a transient species in oxygenated waters, existing at low picomolar concentrations, and therefore undertaking measurements that do not perturb the redox balance is extremely challenging. This project will use robust and automated instrumentation, developed by the applicants, to measure the concentrations of iron species (particularly Fe(II), colloidal and soluble fractions) in surface waters of the Atlantic Ocean and correlate these data with productivity (determined by measuring e.g. chlorophyll a). It will also investigate the nature and quantity of iron binding chemicals (siderophores) released by marine bacteria. It is essential that iron data are of high quality and the research will therefore include rigorous intercomparison exercises with other expert laboratories to harmonise results reported by different research groups.
Period of Award:
1 Apr 2004 - 30 Sep 2007
Value:
£205,337
Authorised funds only
NERC Reference:
NER/A/S/2003/00489
Grant Stage:
Completed
Scheme:
Standard Grants Pre FEC
Grant Status:
Closed
Programme:
Standard Grant

This grant award has a total value of £205,337  

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FDAB - Financial Details (Award breakdown by headings)

Total - T&STotal - StaffTotal - Other CostsTotal - EquipmentTotal - Indirect Costs
£22,711£87,537£25,172£13,090£56,827

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