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Details of Award

NERC Reference : NE/V000411/1

Finding the missing evidence for Earth's magma ocean: a novel stable isotope approach

Grant Award

Principal Investigator:
Professor HM Williams, University of Cambridge, Earth Sciences
Co-Investigator:
Dr O Shorttle, University of Cambridge, Earth Sciences
Co-Investigator:
Dr FE Jenner, The Open University, Faculty of Sci, Tech, Eng & Maths (STEM)
Science Area:
Earth
Overall Classification:
Panel A
ENRIs:
Global Change
Natural Resource Management
Science Topics:
Mantle & Core Processes
Deep mantle processes
Earth history
Extreme pressures
Geochemistry
Magmatism
Mantle composition
Mantle convection
Mantle plumes
Phase transitions
Trace elements
Volcanic Processes
Mantle plumes
Noble gases
Non-radiogenic isotopes
Oxygen fugacity
Trace elements
Abstract:
Earth's present belies its violent past. Catastrophic impacts during the Earth's first 500 million years generated enough energy to melt the planet's interior, creating planetary-scale volumes of melt, or "magma oceans". Their subsequent cooling and crystallisation would have set the chemistry of the Earth and its future long-term habitability. However, we do not know exactly where and how the Earth's magma oceans crystallised, what their composition was and whether remnants of early magma ocean material remain present in the Earth's deep interior, potentially acting as important reservoirs for volatiles and precious metals. A key piece of information may reside in the deep Earth: as the magma ocean cooled it would have started to crystallise, with the dense newly formed crystals sinking to the base of Earth's mantle. This would have generated strong chemical layering in the mantle, which could persist to today. This project focuses on finding the chemical evidence for these piles of dense magma ocean crystals, and thus identifying a key missing piece of evidence for Earth's earliest history. As the deepest mantle is inaccessible to direct sampling, we must rely on nature to do this for us. This occurs when regions of the mantle heat up, buoyantly rise and melt, ultimately producing volcanism; a phenomenon exhibited at Iceland, Hawaii and other "mantle plumes". We can use the chemistry of these lavas to probe the composition of the material that melted to form them, thereby gaining a window into the deep Earth. The chemical signals in both modern and ancient lavas have resulted in the paradigm of isolated and "primordial" regions of the Earth's interior, often presumed to be located at the very base of the Earth's mantle, at the boundary with the planet's central metallic core. It has been suggested that the mineralogy and composition of these deep mantle domains has allowed them to resist being entrained into the convecting mantle for billions of years, where they may store volatile- and heat-producing elements. Do these regions of the Earth's mantle have their origin in magma ocean crystallisation? Has magma ocean material always remained isolated from the convecting mantle? Can residual frozen melts or crystalline material left over from magma ocean crystallisation be transported into the upper mantle, and if so, can it melt and contribute to the chemistry of modern and ancient primitive lavas? To answer these questions, we need chemical tracers that, 1) respond directly to the type of minerals that would have formed during the crystallisation of a deep magma ocean, 2) are resistant to alteration when volcanic rocks are weathered at Earth's surface so that they can be applied to ancient lavas, and 3) reflect the bulk properties of the mantle that these lavas were derived from. We propose to use iron (Fe) and calcium (Ca) stable isotopes as tracers. Reconnaissance measurements of 3.7 billion year old rocks shows that these tracers are robust to the rocks' weathering history. The data also contain the tantalising suggestion that these volcanics were derived from melting material residual from a former magma ocean. We will use these tracers to explore the Earth's magma ocean history and its role in defining the chemical and physical state of the planet today. Important steps are: 1) Constraining the partitioning of Fe and Ca isotopes during magma ocean crystallisation. We will do this by high-pressure laboratory experiments, where we will simulate the conditions of magma ocean crystallisation and analyse the crystal residues that we produce. 2) Undertaking new Fe and Ca isotope analysis of volcanics ranging from 3.7 billion years old to the present. 3) Develop a series of thermodynamic models to track the Fe and Ca isotope effects of magma ocean crystallisation and to predict the composition of volcanics derived from the entrainment and melting of these magma ocean crystal piles in the upper mantle.
Period of Award:
1 Apr 2021 - 31 Mar 2025
Value:
£617,419
Authorised funds only
NERC Reference:
NE/V000411/1
Grant Stage:
Awaiting Event/Action
Scheme:
Standard Grant FEC
Grant Status:
Active
Programme:
Standard Grant

This grant award has a total value of £617,419  

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FDAB - Financial Details (Award breakdown by headings)

DI - Other CostsIndirect - Indirect CostsDA - InvestigatorsDA - Estate CostsDI - StaffDI - T&SDA - Other Directly Allocated
£67,783£219,710£42,764£51,160£166,629£24,879£44,494

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