Details of Award
NERC Reference : NE/P002331/1
How did primordial and recycled geochemical signatures come to coexist in the Earth's deep mantle?
Grant Award
- Principal Investigator:
- Dr ME Hartley, The University of Manchester, Earth Atmospheric and Env Sciences
- Co-Investigator:
- Professor R Burgess, The University of Manchester, Earth Atmospheric and Env Sciences
- Co-Investigator:
- Dr G Holland, The University of Manchester, Earth Atmospheric and Env Sciences
- Grant held at:
- The University of Manchester, Earth Atmospheric and Env Sciences
- Science Area:
- Earth
- Overall Classification:
- Panel A
- ENRIs:
- Environmental Risks and Hazards
- Global Change
- Science Topics:
- Analytical Science
- Chemical Data Analysis
- Mass Spectrometry
- Deep mantle processes
- Earth history
- Geochemistry
- Mantle & Core Processes
- Magmatism
- Mantle composition
- Mantle plumes
- Ocean ridge volcanism
- Noble gases
- Volcanic gases
- Volcanic Processes
- Abstract:
- The transport and cycling of volatile elements between the solid Earth, oceans and atmosphere has shaped the evolution of our planet. Chemical fluxes of volatiles to and from long-term mantle reservoirs are maintained by convective and tectonic processes. However, the mechanisms that control the volatile budgets of distinct mantle reservoirs remain uncertain. Major questions include: How did the Earth acquire its initial volatile inventory? What was the closure age of the mantle to atmosphere loss? How has crustal recycling modified mantle volatile reservoirs? What is the spatial distribution of primordial and recycled volatiles in the mantle? The key objective of this project is to provide a new understanding of spatial and temporal relationships between primordial and recycled sources in the Earth's mantle, underpinned by high-precision geochemical data and detailed statistical modelling. We will achieve this by interrogating combined noble gas isotope compositions and halogen contents in an exceptional suite of subglacially erupted basalts from Iceland that map a high-resolution transect across a mantle plume. The samples preserve geochemical signatures of melts from both ancient sources and the shallow convecting mantle, which has been extensively modified by melt extraction and recycling over geologic time. The unparalleled high-resolution, spatially continuous sample of the mantle afforded by erupted basalts from Iceland's neovolcanic zones makes Iceland an ideal natural laboratory for investigating the history of accretion, differentiation, outgassing and recycling in the mantle. The inert noble gases (He, Ne, Ar, Kr, Xe) provide key geochemical tracers of primordial mantle domains that have remained largely unmodified since the Earth's formation. In contrast, fluid-mobile halogens (F, Cl, Br, I) are reintroduced to the mantle by the subduction of seawater, sediment and altered oceanic crust at destructive plate boundaries, and are therefore key tracers of recycled material in the mantle. There is at present an unresolved dichotomy between existing interpretations of noble gases, halogens and other geochemical tracers such as lithophile isotopes (Sr, Nd, Pb). Lithophile isotopes and halogens provide abundant evidence that mixing, stretching and recycling in the mantle has created highly heterogeneous lithological and spatial structure beneath Iceland. However, noble gas isotopes indicate that some parts of the Icelandic mantle retain primordial, unprocessed geochemical signatures. A crucial limitation of previous work is that lithophile elements and isotopes, major volatiles and noble gases have been analysed in different sample sets, such that we cannot combine the sensitivities of different elements to obtain robust constraints on mantle sources. By bringing these data into a single coherent framework, this project provides the first opportunity to interrogate simultaneously multiple geochemical proxies to probe the spatial and temporal relationships between primordial and recycled mantle sources. We will use state-of-the-art mass spectrometry techniques to provide new independent constraints on halogen and noble gas decoupling in the mantle, and the extent of halogen loss from different mantle reservoirs in the early Earth. We will provide the first high-precision analysis of the Kr-isotopic composition of the Earth's primordial mantle, and a new, precise determination of iodine abundance in the mantle. We will perform the first combined spatial statistics analysis of noble gas, halogen and lithophile isotope data to determine the location and distribution of primordial and recycled reservoirs in a mantle plume, providing key insights into the structure and dynamics of the mantle. Our results will provide a guide to interpreting mantle geochemical and spatial structure at other ocean islands on Earth, and will feed into ongoing efforts to model volatile budgets and volatile cycling on other planetary bodies.
- NERC Reference:
- NE/P002331/1
- Grant Stage:
- Completed
- Scheme:
- Standard Grant FEC
- Grant Status:
- Closed
- Programme:
- Standard Grant - NI
This grant award has a total value of £393,157
FDAB - Financial Details (Award breakdown by headings)
| DI - Other Costs | Indirect - Indirect Costs | DA - Investigators | DI - Staff | DA - Estate Costs | DI - T&S | DA - Other Directly Allocated |
|---|---|---|---|---|---|---|
| £22,491 | £116,861 | £46,881 | £102,859 | £43,393 | £28,277 | £32,395 |
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