Details of Award
NERC Reference : NE/N017293/1
NANODOT2: NANOMATERIALS FOR THE RADIOMETRIC DETECTION OF TRITIUM
Grant Award
- Principal Investigator:
- Professor C Boxall, Lancaster University, Engineering
- Co-Investigator:
- Professor MJ Joyce, Lancaster University, Engineering
- Co-Investigator:
- Dr JM Pates, Lancaster University, Lancaster Environment Centre
- Grant held at:
- Lancaster University, Engineering
- Science Area:
- Marine
- Terrestrial
- Overall Classification:
- Unknown
- ENRIs:
- Environmental Risks and Hazards
- Pollution and Waste
- Science Topics:
- Electroanalysis
- Analytical Science
- CCD
- Chemical Sensors
- Environmental Sensors
- Radionucleide Imaging Instrum.
- Instrumentation Eng. & Dev.
- Contaminated Land
- Assess/Remediate Contamination
- Nanoporous Materials
- Materials Synthesis & Growth
- Groundwater pollution
- Drinking water
- Water Quality
- Abstract:
- This project, NANODOT2 (NANOmaterials for the radiometric Detection Of TriTium) aims to exploit recent advances in nanomaterials fabrication to develop a novel, prototype instrument for the analysis and characterisation of radioactive tritium in the terrestrial and marine environments around both operational nuclear facilities and those in decommissioning. Falling squarely within NERC's remit, NANODOT2 is a 12 month follow project from an earlier NERC-funded PhD and is a collaboration between Lancaster University and Hybrid Instruments, an SME specialising in the manufacture and marketing of advanced radiometric instrumentation. Tritium (T) is a radioactive isotope of hydrogen made during the routine operation of nuclear reactors. This can give rise to waterborne tritium in, inter alia, spent fuel (SF) cooling ponds and SF processing & waste treatment facilities - all potential sources of leakage to ground and beyond. Waterborne T is most commonly present in groundwater in the form of tritiated water, HTO. As T is an isotope of H, HTO behaves indistinguishably from H2O and so is highly mobile in the environment, its migration rate being identical to the velocity of groundwater due to the HTO/H2O equivalency. This also makes HTO highly mobile in human tissue, with associated health risks - the WHO limit for T in drinking water is <10 kBq/L. Additionally, despite often being present in extremely low quantity as a result of anthropogenic activities and easily dispersed, tritium is a concern to many industries i.e. sea fisheries often commanding extensive clean-up even where it is present at less than accepted statutory limits. Thus there are pressing health & safety and economic needs for fast, accurate & precise analysis of T in the terrestrial and marine environments around nuclear sites and in the wastes arising from their operation/decommissioning. Lancaster and Hybrid have been working in collaboration for >4 years to address these needs. Tritium decays with a soft beta emission making rapid radiometric detection in the field very difficult. However, data from a very successful NERC/RSC ACTF PhD studentship (award NE/H025650/1, hereafter NANODOT1) conducted at Lancaster with Hybrid, provide PROOF OF PRINCIPLE that, by electrolysis, T can be selectively & reversibly sequestered by nanoporous palladium (Pd) layers from HTO, the pre-concentrated T then being easily detected by liquid scintillation counting. A subsequent InnovateUK/Nuclear Decommissioning Authority funded feasibility study (award 131756, TRIBECA, TRItium detection By Electro-Chemically Assisted radiometrics), again conducted by Lancaster & Hybrid, demonstrated the possibility of coupling nanoporous Pd layers directly to solid scintillators. This provided a means by which T could be pre-concentrated at a scintillator surface prior to analysis by PMT-based solid scintillation counting, potentially yielding a novel radiometric instrument for T detection offering fast, interference free, in situ detection & monitoring. TRIBECA also demonstrated the market for such a tritium sensor and its underpinning technology, and led to a UK patent application GB2523732 "Tritium Measurement". NANODOT1 took this technology to (Technology Readiness Level) TRL3 (feasibility) whilst TRIBECA further advanced it to TRL5 (component development). NANODOT2 aims to take the technology to TRL6 (demonstration). Specifically, we aim to build a prototype instrument that, based on a novel Pd nanomaterial-modified solid scintillator for beta radiation detection, offers: -cheaper, faster, more sensitive & more reliable T detection than current technology; and -fast, accurate & precise measurement of waterborne T for environmental analysis and nuclear waste/process/effluent stream characterisation. Keywords: Tritium Detection; Environmental Radioactivity; Analytical Science; Environmental Monitoring; Nanomaterials Stakeholders: Lancaster University, Hybrid Instruments
- NERC Reference:
- NE/N017293/1
- Grant Stage:
- Completed
- Scheme:
- Innovation
- Grant Status:
- Closed
- Programme:
- Follow on Fund
This grant award has a total value of £99,341
FDAB - Financial Details (Award breakdown by headings)
| DI - Other Costs | Indirect - Indirect Costs | DA - Investigators | DA - Estate Costs | DI - Staff | DI - T&S | DA - Other Directly Allocated |
|---|---|---|---|---|---|---|
| £24,436 | £28,886 | £2,033 | £14,061 | £27,691 | £1,613 | £621 |
If you need further help, please read the user guide.