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Details of Award

NERC Reference : NE/E014909/1

Total Radical Production and Degradation Products from Alkene Ozonolysis

Grant Award

Principal Investigator:
Professor W Bloss, University of Leicester, Chemistry
Co-Investigator:
Professor PS Monks, University of Leicester, Chemistry
Science Area:
Atmospheric
Overall Classification:
Atmospheric
ENRIs:
Pollution and Waste
Global Change
Science Topics:
Pollution
Tropospheric Processes
Atmospheric Kinetics
Biogeochemical Cycles
Abstract:
Atmospheric composition is determined by a combination of emissions and chemical processing within the atmosphere. The removal of most hydrocarbons emitted to the atmosphere is initiated by reaction with the hydroxyl radical (OH). A series of degradation steps follows, leading eventually to CO2 and water. In the presence of nitrogen oxides, hydrocarbon oxidation leads to production of ozone / a pollutant harmful to human health, vegetation and materials. The extent to which ozone formation occurs depends upon details of the hydrocarbon oxidation steps. OH is formed naturally through the action of sunlight upon ozone. Following reaction with hydrocarbons, OH is converted into HO2 and RO2, hydro and organic peroxy radicals. RO2 and HO2 can then be converted back into OH if moderate levels of NO are present / an example of radical cycling. OH levels control the abundance of pollutants and global warming gases such as methane, and limit the rate of ozone production. To quantify these effects, we need to understand the processes which govern OH levels, while to predict the atmospheric impact of a given hydrocarbon, we must identify its degradation products / e.g., to assess if they have a long enough lifetime to be transported from their point of origin.
Period of Award:
17 Dec 2007 - 16 Dec 2010
Value:
£96,168 Split Award
Authorised funds only
NERC Reference:
NE/E014909/1
Grant Stage:
Completed
Scheme:
Standard Grant (FEC)
Grant Status:
Closed
Programme:
Standard Grant

This grant award has a total value of £96,168  

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FDAB - Financial Details (Award breakdown by headings)

DI - Other CostsIndirect - Indirect CostsDA - InvestigatorsDA - Estate CostsDI - StaffDA - Other Directly AllocatedDI - T&S
£13,306£32,641£5,710£10,845£23,938£2,754£6,975

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