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Details of Award

NERC Reference : NE/E011489/1

A comparison of sea to air DMS flux measurements and the possible role of near- surface gradients

Grant Award

Principal Investigator:
Professor PD Nightingale, Plymouth Marine Laboratory, Plymouth Marine Lab
Co-Investigator:
Dr S Archer, Bigelow Lab for Ocean Sciences, UNLISTED
Science Area:
Marine
Atmospheric
Overall Classification:
Marine
ENRIs:
Global Change
Science Topics:
Boundary Layer Meteorology
Biogeochemical Cycles
Ocean - Atmosphere Interact.
Abstract:
The rates at which gases exchange between the oceans and the atmosphere are extremely important to global biogeochemical cycles and to predicting and modelling future climate change, but quantifying them accurately currently remains elusive. Some important issues requiring accurate estimates include the rate at which anthropogenic carbon dioxide can be taken up by the oceans and quantifying the marine sources of other important climate active gases such as dimethyl sulphide that scientists believe control cloud formation over the oceans. We plan to measure concentrations of DMS in the water so that we can use this data, together with a new technique for measuring the air-sea flux of DMS to be made by our project partners from the University of Hawaii, in order to better understand the processes that control the transfer of gases between the atmosphere and the ocean. We think that as well as the wind, the amounts of bubbles made by breaking waves will have an important impact on air--sea gas exchange. Much of the data on the amount of DMS that is present in seawater is collected from water pumped into research ships from the bottom of the ship. This is usually at a depth of about 5-8m. However, in order to calculate the amount of DMS that is transferring from the sea to the air we really need to know the concentration of this gas at the sea surface. Everybody assumes that the concentrations measurements from the ship's hull (ie 5-8m) are the same as those made at the sea surface. However, we know that DMS is produced and consumed by biological processes in the water and that it is rapidly destroyed by sunlight. We therefore want to check whether there is a difference between dimethyl sulphide concentrations at the sea surface compared to the depths of ship hulls. This would be have important consequences for calcuating the actual amount of dimethyl sulphide that the ocean supplies to the atmosphere. It is also important to know if there are any gradients when we want to compare the direct estimates of the DMS flux with the indirect estimates as this would impact on how important we think the bubbles might be in air-sea gas transfer. We plan to participate in a research cruisein the North Atlantic Ocean in the suimmer of 2007 when there will be many other groups making a variety of key measurements and observations (measure seastate, whitecapping and wave breaking and evaluating the role of bubbles and surfactants air-sea gas exchange.
Period of Award:
1 Apr 2007 - 30 Jun 2009
Value:
£99,720
Authorised funds only
NERC Reference:
NE/E011489/1
Grant Stage:
Completed
Scheme:
Directed (Research Programmes)
Grant Status:
Closed
Programme:
SOLAS

This grant award has a total value of £99,720  

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FDAB - Financial Details (Award breakdown by headings)

DI - Other CostsIndirect - Indirect CostsDI - EquipmentDI - StaffDA - Estate CostsDI - T&S
£11,974£18,392£3,572£42,659£19,807£3,314

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