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Details of Award

NERC Reference : NE/C510583/1

Unravelling the Ca isotope curve: shoring up global budgets and identifying responses to long- and short-term climatic perturbations.

Grant Award

Principal Investigator:
Professor MJ Bickle, University of Cambridge, Earth Sciences
Co-Investigator:
Professor H Elderfield, University of Cambridge, Earth Sciences
Co-Investigator:
Dr A Tripati, University of California Los Angeles, UNLISTED
Co-Investigator:
Dr A Galy, University of Cambridge, Earth Sciences
Science Area:
Marine
Freshwater
Overall Classification:
Marine
ENRIs:
Global Change
Science Topics:
Biogeochemical Cycles
Ocean - Atmosphere Interact.
Climate & Climate Change
Abstract:
The last ~55 million years have! seen a significant drop in global average temperatures by 15?C. One of the big questions that remains to be answered is to what extent this can be explained by a change in the relationship between temperature and the rates of weathering of silicate rocks. Atmospheric CO2 is consumed during weathering and it is thought that, if weathering rates are high when temperatures are warm (and if the converse), then this may have provided a negative feedback operating to limit major glaciations and stabilize climatic fluctuations. However, the uplift of large mountain belts such as the Himalayas may have resulted in elevated weathering rates that were sustained at low temperatures, and caused this long-term global cooling. Superimposed on this drop in temperatures are periods of rapid global change that lasted a few hundred thousand years , when weathering rates have changed dramatically and ocean pH has changed, such as when ice sheets on Antarctica have expanded. The magnitude of these climatic events, and the relationship between rapid climate changes, ocean chemistry, and weathering rates, are just beginning to be explained. The work we propose will study both the long-term changes and the severe, abrupt disturbances in the climate-weathering-ocean chemistry system. We will track changes in the concentration of dissolved calcium in seawater by looking at changes in the ratio of two stable isotopes of calcium (44Ca and 42Ca) in calcium carbonate deposited in seafloor sediments. Changes in the 44Ca/42Ca ratio will help us to identify times when the input to the ocean of dissolved calcium weathered from rocks is unequal to the output of dissolved calcium from the ocean in the form of carbonate sediments. Such imbalances should occur during those times when climate is changing and affecting weathering rates, and also when atmospheric CO2 changes are affecting the formation and preservation of carbonate sediments in the ocean. Supporting the work on the sediments, we will also determine the 44Ca/42Ca ratio of the major inputs and outputs of calcium to the ocean: river waters, hydrothermal fluids, arid sedimentary calcite and aragonite. This survey will allow us to greatly improve our understanding of the isotopic composition of all these materials and put limits on our expectation of the 44Ca/42Ca changes in seawater due to perturbations to the global calcium cycle We will also model these changes, using a basic model of inputs and outputs and include the climatic controls on carbonate sedimentation.
Period of Award:
1 Jan 2005 - 31 Dec 2008
Value:
£150,801
Authorised funds only
NERC Reference:
NE/C510583/1
Grant Stage:
Completed
Scheme:
Standard Grants Pre FEC
Grant Status:
Closed
Programme:
Standard Grant

This grant award has a total value of £150,801  

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FDAB - Financial Details (Award breakdown by headings)

Total - StaffTotal - T&STotal - Other CostsTotal - EquipmentTotal - Indirect Costs
£73,320£4,293£17,900£21,562£33,726

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