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Details of Award

NERC Reference : NE/B50582X/1

LC-MS/MS for the atmospheric measurement of peroxides and other water soluble molecules.

Grant Award

Principal Investigator:
Professor LJ Carpenter, University of York, Chemistry
Co-Investigator:
Professor A Lewis, University of York, Chemistry
Science Area:
Atmospheric
Overall Classification:
Atmospheric
ENRIs:
Pollution and Waste
Global Change
Science Topics:
Tropospheric Processes
Technol. for Environ. Appl.
Abstract:
A wide range of highly water soluble species are formed in the atmosphere resulting from gas phase oxidation processes often involving organic compounds. Of all the water soluble classes it is peroxides which are perhaps the least well characterised in the atmosphere and provide the greatest analytical challenge. There is a current lack of specific analytical methodology to provide a positive identification of peroxide chemical structures, and a high degree of uncertainty in the quantification of these compounds. In this project we will investigate liquid chromatography coupled to tandem mass spectrometry as a method for positive identification and measurement of peroxides in air. The techniques developed in tackling this problem will be widely transferable and in parallel methodologies will be developed for the positive identification of other electronegative molecules such as organic acids, which are key species in gas to particle transfer of organic material. The development of analytical methods for resolving compounds such as speciated peroxides, organic acids and other small polar molecules will add considerably to the UK atmospheric chemistry measurement capability.
Period of Award:
13 Dec 2004 - 12 Dec 2007
Value:
£396,658
Authorised funds only
NERC Reference:
NE/B50582X/1
Grant Stage:
Completed
Scheme:
Capital Equipment Pre FEC
Grant Status:
Closed

This grant award has a total value of £396,658  

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FDAB - Financial Details (Award breakdown by headings)

Total - T&STotal - StaffTotal - Other CostsTotal - Indirect CostsTotal - Equipment
£624£96,076£25,291£44,196£230,470

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